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    Hydrolysis of Evaporated Zn in a Hot Wall Flow Reactor

    Source: Journal of Solar Energy Engineering:;2008:;volume( 130 ):;issue: 004::page 41010
    Author:
    Tareq Abu Hamed
    ,
    Jane H. Davidson
    ,
    Mark Stolzenburg
    DOI: 10.1115/1.2969808
    Publisher: The American Society of Mechanical Engineers (ASME)
    Abstract: Hydrolysis of Zn is investigated as the second step in a ZnO∕Zn redox solar water splitting process. Zinc is evaporated and hydrolyzed with steam in a hot wall flow tubular reactor. The influence of the reactor temperature distribution and residence time on hydrogen conversion was measured for furnace set point temperatures of 1023K and 1073K. The yield of ZnO aerosol was measured in situ using a scanning differential mobility sizer. The composition and morphology of the solid product were characterized with X-ray diffraction and microscopy. Hydrogen conversions of 87–96% at temperatures above zinc saturation are attributed primarily to hydrolysis of zinc(g) at the wall of the reactor at temperatures from 800Kto1077K.
    keyword(s): Flow (Dynamics) , Temperature , Particulate matter , Furnaces , Hydrogen , Hydrogen production , Steam , Aerosols , Solar energy , Water , X-ray diffraction AND Evaporation ,
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      Hydrolysis of Evaporated Zn in a Hot Wall Flow Reactor

    URI
    http://yetl.yabesh.ir/yetl1/handle/yetl/139266
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    contributor authorTareq Abu Hamed
    contributor authorJane H. Davidson
    contributor authorMark Stolzenburg
    date accessioned2017-05-09T00:30:23Z
    date available2017-05-09T00:30:23Z
    date copyrightNovember, 2008
    date issued2008
    identifier issn0199-6231
    identifier otherJSEEDO-28415#041010_1.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/139266
    description abstractHydrolysis of Zn is investigated as the second step in a ZnO∕Zn redox solar water splitting process. Zinc is evaporated and hydrolyzed with steam in a hot wall flow tubular reactor. The influence of the reactor temperature distribution and residence time on hydrogen conversion was measured for furnace set point temperatures of 1023K and 1073K. The yield of ZnO aerosol was measured in situ using a scanning differential mobility sizer. The composition and morphology of the solid product were characterized with X-ray diffraction and microscopy. Hydrogen conversions of 87–96% at temperatures above zinc saturation are attributed primarily to hydrolysis of zinc(g) at the wall of the reactor at temperatures from 800Kto1077K.
    publisherThe American Society of Mechanical Engineers (ASME)
    titleHydrolysis of Evaporated Zn in a Hot Wall Flow Reactor
    typeJournal Paper
    journal volume130
    journal issue4
    journal titleJournal of Solar Energy Engineering
    identifier doi10.1115/1.2969808
    journal fristpage41010
    identifier eissn1528-8986
    keywordsFlow (Dynamics)
    keywordsTemperature
    keywordsParticulate matter
    keywordsFurnaces
    keywordsHydrogen
    keywordsHydrogen production
    keywordsSteam
    keywordsAerosols
    keywordsSolar energy
    keywordsWater
    keywordsX-ray diffraction AND Evaporation
    treeJournal of Solar Energy Engineering:;2008:;volume( 130 ):;issue: 004
    contenttypeFulltext
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