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    Effects of Organic Cation Structure on Behavior of Organobentonites

    Source: Journal of Geotechnical and Geoenvironmental Engineering:;2001:;Volume ( 127 ):;issue: 004
    Author:
    Natalie M. Soule
    ,
    Susan E. Burns
    DOI: 10.1061/(ASCE)1090-0241(2001)127:4(363)
    Publisher: American Society of Civil Engineers
    Abstract: This study quantified the effects of four quaternary ammonium cations (TMA, DTMA, HDTMA, and BTEA) on the mechanical properties of a modified Wyoming bentonite. TMA, DTMA, and HDTMA are organic cations with alkyl chains of lengths 1, 10, and 16 carbons, while BTEA has a benzyl ring attached. Substitution of the organic cations onto the bentonite surfaces altered the soil's behavior by: (1) reducing the soil's specific gravity, with the specific gravity decreasing linearly as the size of the exchanged organic cation was increased; (2) dramatically reducing the soil's liquid limit (from 458% for the unmodified bentonite to 52–65% for the organoclays); (3) reducing the compressibility of the clays (from a compression index of 5.5 for the unmodified bentonite to compression indices of 0.47–0.59 for the organoclays); (4) reducing the swell potential (
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      Effects of Organic Cation Structure on Behavior of Organobentonites

    URI
    http://yetl.yabesh.ir/yetl1/handle/yetl/52032
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    • Journal of Geotechnical and Geoenvironmental Engineering

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    contributor authorNatalie M. Soule
    contributor authorSusan E. Burns
    date accessioned2017-05-08T21:27:13Z
    date available2017-05-08T21:27:13Z
    date copyrightApril 2001
    date issued2001
    identifier other%28asce%291090-0241%282001%29127%3A4%28363%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/52032
    description abstractThis study quantified the effects of four quaternary ammonium cations (TMA, DTMA, HDTMA, and BTEA) on the mechanical properties of a modified Wyoming bentonite. TMA, DTMA, and HDTMA are organic cations with alkyl chains of lengths 1, 10, and 16 carbons, while BTEA has a benzyl ring attached. Substitution of the organic cations onto the bentonite surfaces altered the soil's behavior by: (1) reducing the soil's specific gravity, with the specific gravity decreasing linearly as the size of the exchanged organic cation was increased; (2) dramatically reducing the soil's liquid limit (from 458% for the unmodified bentonite to 52–65% for the organoclays); (3) reducing the compressibility of the clays (from a compression index of 5.5 for the unmodified bentonite to compression indices of 0.47–0.59 for the organoclays); (4) reducing the swell potential (
    publisherAmerican Society of Civil Engineers
    titleEffects of Organic Cation Structure on Behavior of Organobentonites
    typeJournal Paper
    journal volume127
    journal issue4
    journal titleJournal of Geotechnical and Geoenvironmental Engineering
    identifier doi10.1061/(ASCE)1090-0241(2001)127:4(363)
    treeJournal of Geotechnical and Geoenvironmental Engineering:;2001:;Volume ( 127 ):;issue: 004
    contenttypeFulltext
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