Fabrication Aspects and Performance Characterization of α-Al2O3/AlPO4 Based Sandwich Configuration Flow Channel Inserts and Coatings for High Temperature Liquid Metal Applications

Abstract

Liquid metals (LMs) exhibit several key characteristics justifying their utilization as coolants and breeders for nuclear fusion reactors and advanced fission reactors. In fusion reactors, the LMs confront an exorbitantly high flow retarding force, due to the magneto-hydro-dynamics (MHD) effect, imposing significant demands on the pumping power and designs of ancillary coolant systems. Corrosion of structural materials leading to activated corrosion products and coolant chemistry control are some of the vital issues common to both fusion and fission reactors employing liquid lead (Pb) and its alloys. To address these concerns, different technological solutions such as flow channel inserts (FCIs) and high temperature compatible corrosion resistant coatings are being investigated to provide a chemical and/or electrical isolation between the LM and structural material for advanced reactors. In this study, three different prototype geometries (circular, square, and 90 deg bend) of steel-insulator-steel sandwich FCIs are fabricated for fusion reactor applications and an extensive characterization of the electrical insulation is performed over an operating temperature range of 100 °C–600 °C. Welding trials and pneumatic pressure tests up to 10 kg/cm2 (g) are performed on the assemblies to validate the electrical and mechanical integrity over typical fusion reactor operational regime. This paper presents detailed fabrication aspects along with quantitative estimations of insulation filling density, electrical insulation performance and, for the first time, a detailed systematic study of insulation degradation resulting from the combined effects of tungsten inert gas (TIG) welding, exposure to pressure and machining operations on these FCIs. The paper also provides critical details derived from the metallurgical examinations and visual observations from the destructive tests executed on the prototypes. Further, from an implementation perspective toward Lead-cooled Fast Reactors (LFRs), a preliminary feasibility assessment of the α-Al2O3/AlPO4 coating is performed through thin film deposition trials on planar and non-planar substrates followed by mechanical characterizations, such as coating thickness, surface roughness, adhesion strength and microhardness. Metallurgical analyses are presented and discussed to assess Pb ingress after 700 h of continuous exposure to molten Pb alloy at 300 °C–400 °C.