Effects of Snow Cover and Atmospheric Stability on Winter PM2.5 Concentrations in Western U.S. Valleys

Abstract

any populated valleys in the western United States experience increased concentrations of particulate matter with diameter of less than 2.5 ?m (PM2.5) during winter stagnation conditions. Further study into the chemical components composing wintertime PM2.5 and how the composition and level of wintertime PM2.5 are related to meteorological conditions can lead to a better understanding of the causes of high PM2.5 and aid in development and application of emission controls. The results can also aid in short-term air-pollution forecasting and implementation of periodic emission controls such as burning bans. This study examines relationships between PM2.5 concentrations and wintertime atmospheric stability (defined by heat deficit) during snow-covered and snow-free conditions from 2000 to 2013 for five western U.S. urbanizations: Salt Lake City, Utah; Reno, Nevada; Boise, Idaho; Missoula, Montana; and Spokane, Washington. Radiosonde data were used where available to calculate daily heat deficit, which was compared with PM2.5 concentration for days with snow cover and days with no snow cover. Chemically speciated PM2.5 data were compared for snow-cover and snow-free days to see whether the chemical abundances varied by day category. Wintertime PM2.5 levels were highly correlated with heat deficit for all cities except Spokane, where the airport sounding does not represent the urban valley. For a given static stability, snow-cover days experienced higher PM2.5 levels than did snow-free days, mainly because of enhanced ammonium nitrate concentrations. Normalizing average PM2.5 to the heat deficit reduced year-to-year PM2.5 variability, resulting in stronger downward trends, mostly because of reduced carbonaceous aerosol concentrations. The study was limited to western U.S. cities, but similar results are expected for other urban areas in mountainous terrain with cold, snowy winters.