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    On the Thermodynamics of Nucleation in Weak Gas-Liquid Solutions

    Source: Journal of Fluids Engineering:;1970:;volume( 092 ):;issue: 004::page 695
    Author:
    C. A. Ward
    ,
    A. Balakrishnan
    ,
    F. C. Hooper
    DOI: 10.1115/1.3425107
    Publisher: The American Society of Mechanical Engineers (ASME)
    Abstract: Gas-vapor nucleation in liquid solutions is considered. It is shown that for nucleation to occur in a multicomponent solution a nucleus must be created of at least a certain radius. Consideration is then restricted to weak solutions of gas dissolved in liquids with the gas allowed to behave nonideally. A generalized Kelvin equation is derived which relates the partial pressure of the solvent vapor inside a nucleus to the properties of the surrounding solution. It is shown how, for a given temperature, the pressure at which nucleation occurs in a gas-liquid solution is increased as the gas concentration is increased.
    keyword(s): Thermodynamics , Nucleation (Physics) , Pressure , Vapors , Temperature AND Equations ,
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      On the Thermodynamics of Nucleation in Weak Gas-Liquid Solutions

    URI
    http://yetl.yabesh.ir/yetl1/handle/yetl/142890
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    • Journal of Fluids Engineering

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    contributor authorC. A. Ward
    contributor authorA. Balakrishnan
    contributor authorF. C. Hooper
    date accessioned2017-05-09T00:37:08Z
    date available2017-05-09T00:37:08Z
    date copyrightDecember, 1970
    date issued1970
    identifier issn0098-2202
    identifier otherJFEGA4-27372#695_1.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/142890
    description abstractGas-vapor nucleation in liquid solutions is considered. It is shown that for nucleation to occur in a multicomponent solution a nucleus must be created of at least a certain radius. Consideration is then restricted to weak solutions of gas dissolved in liquids with the gas allowed to behave nonideally. A generalized Kelvin equation is derived which relates the partial pressure of the solvent vapor inside a nucleus to the properties of the surrounding solution. It is shown how, for a given temperature, the pressure at which nucleation occurs in a gas-liquid solution is increased as the gas concentration is increased.
    publisherThe American Society of Mechanical Engineers (ASME)
    titleOn the Thermodynamics of Nucleation in Weak Gas-Liquid Solutions
    typeJournal Paper
    journal volume92
    journal issue4
    journal titleJournal of Fluids Engineering
    identifier doi10.1115/1.3425107
    journal fristpage695
    journal lastpage701
    identifier eissn1528-901X
    keywordsThermodynamics
    keywordsNucleation (Physics)
    keywordsPressure
    keywordsVapors
    keywordsTemperature AND Equations
    treeJournal of Fluids Engineering:;1970:;volume( 092 ):;issue: 004
    contenttypeFulltext
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