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    HPLC Determination of Atmospheric Organic Hydroperoxides

    Source: Journal of Atmospheric and Oceanic Technology:;1995:;volume( 012 ):;issue: 002::page 282
    Author:
    Kok, Gregory L.
    ,
    McLaren, Scott E.
    ,
    Stafflbach, Thomas A.
    DOI: 10.1175/1520-0426(1995)012<0282:HDOAOH>2.0.CO;2
    Publisher: American Meteorological Society
    Abstract: A high-performance liquid chromatographic analytical technique has been developed for the separation of hydrogen peroxide and low molecular weight organic hydroperoxides. A total of 10 C1?C3 organic hydroperoxides have been separated. The detection system is based on postcolumn derivatization using an enzymatic reaction with p-hydroxyphenylacelic acid to form a fluorescent dimer. The detection limit for the technique is 9 ? 10?8 M for hydrogen peroxide and 2 ? 10?8 M for other hydroperoxides. This paper details the optimization of the analytical technique, examining column characteristics and the chemistry of the analytical reaction.
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      HPLC Determination of Atmospheric Organic Hydroperoxides

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    https://yetl.yabesh.ir/yetl1/handle/yetl/4145346
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    contributor authorKok, Gregory L.
    contributor authorMcLaren, Scott E.
    contributor authorStafflbach, Thomas A.
    date accessioned2017-06-09T13:58:43Z
    date available2017-06-09T13:58:43Z
    date copyright1995/04/01
    date issued1995
    identifier issn0739-0572
    identifier otherams-1025.pdf
    identifier urihttp://onlinelibrary.yabesh.ir/handle/yetl/4145346
    description abstractA high-performance liquid chromatographic analytical technique has been developed for the separation of hydrogen peroxide and low molecular weight organic hydroperoxides. A total of 10 C1?C3 organic hydroperoxides have been separated. The detection system is based on postcolumn derivatization using an enzymatic reaction with p-hydroxyphenylacelic acid to form a fluorescent dimer. The detection limit for the technique is 9 ? 10?8 M for hydrogen peroxide and 2 ? 10?8 M for other hydroperoxides. This paper details the optimization of the analytical technique, examining column characteristics and the chemistry of the analytical reaction.
    publisherAmerican Meteorological Society
    titleHPLC Determination of Atmospheric Organic Hydroperoxides
    typeJournal Paper
    journal volume12
    journal issue2
    journal titleJournal of Atmospheric and Oceanic Technology
    identifier doi10.1175/1520-0426(1995)012<0282:HDOAOH>2.0.CO;2
    journal fristpage282
    journal lastpage289
    treeJournal of Atmospheric and Oceanic Technology:;1995:;volume( 012 ):;issue: 002
    contenttypeFulltext
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    DSpace software copyright © 2002-2015  DuraSpace
    نرم افزار کتابخانه دیجیتال "دی اسپیس" فارسی شده توسط یابش برای کتابخانه های ایرانی | تماس با یابش
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