Microcosm Approach to Study Transport of Polychlorinated Biphenyls in Sediment

Abstract

The transport of polychlorinated biphenyls (PCBs) in sediment is difficult to study in the laboratory due to their low solubility and strong tendency to sorb to sediment and experimental equipment. A small-scale laboratory microcosm was designed to study PCB transport in anaerobic surface sediment at microscale and to quantify transport rates. Results of verification testing showed that the experimental system enabled quantitative characterization of the diffusive transport of PCBs in sediment in a reasonable time frame (months). The fine-spatial-resolution results obtained were as expected with the less chlorinated, more mobile congeners transporting the fastest and the more heavily chlorinated compounds transporting more slowly. This laboratory microcosm system could be used to study the transport of many types of pollutants in sediment, but is particularly useful for hydrophobic organic compounds.