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    Method for Measuring Air-Immiscible Liquid Partition Coefficients

    Source: Journal of Environmental Engineering:;2006:;Volume ( 132 ):;issue: 001
    Author:
    Michelle A. Simon
    ,
    Mark L. Brusseau
    DOI: 10.1061/(ASCE)0733-9372(2006)132:1(140)
    Publisher: American Society of Civil Engineers
    Abstract: The principal objective of this work was to measure nonaqueous phase liquid-air partition coefficients for various gas tracer compounds. Known amounts of trichloroethene (TCE) and tracer, as neat compounds, were introduced into glass vials and allowed to equilibrate. The TCE and tracer concentration of the headspace was analyzed and the partition coefficient was calculated from a mass balance. The TCE-air partition coefficient, defined as the ratio of the concentration of the tracer in the vapor phase to its concentration in the TCE phase, for gas tracer compounds perfluorodimethylcyclobutane, perfluoromethylcyclopentane, perfluoromethylcyclohexane, dibromodifluoromethane, and dibromotetrafluoroethane were determined to be 22, 24, 53, 370, and 470 for temperatures of
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      Method for Measuring Air-Immiscible Liquid Partition Coefficients

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    contributor authorMichelle A. Simon
    contributor authorMark L. Brusseau
    date accessioned2017-05-08T21:51:07Z
    date available2017-05-08T21:51:07Z
    date copyrightJanuary 2006
    date issued2006
    identifier other%28asce%290733-9372%282006%29132%3A1%28140%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/64253
    description abstractThe principal objective of this work was to measure nonaqueous phase liquid-air partition coefficients for various gas tracer compounds. Known amounts of trichloroethene (TCE) and tracer, as neat compounds, were introduced into glass vials and allowed to equilibrate. The TCE and tracer concentration of the headspace was analyzed and the partition coefficient was calculated from a mass balance. The TCE-air partition coefficient, defined as the ratio of the concentration of the tracer in the vapor phase to its concentration in the TCE phase, for gas tracer compounds perfluorodimethylcyclobutane, perfluoromethylcyclopentane, perfluoromethylcyclohexane, dibromodifluoromethane, and dibromotetrafluoroethane were determined to be 22, 24, 53, 370, and 470 for temperatures of
    publisherAmerican Society of Civil Engineers
    titleMethod for Measuring Air-Immiscible Liquid Partition Coefficients
    typeJournal Paper
    journal volume132
    journal issue1
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(2006)132:1(140)
    treeJournal of Environmental Engineering:;2006:;Volume ( 132 ):;issue: 001
    contenttypeFulltext
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