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    Equilibrium and Heat of Adsorption for Water Vapor and Activated Carbon

    Source: Journal of Environmental Engineering:;2000:;Volume ( 126 ):;issue: 003
    Author:
    Shaoying Qi
    ,
    K. James Hay
    ,
    Mark J. Rood
    ,
    Mark P. Cal
    DOI: 10.1061/(ASCE)0733-9372(2000)126:3(267)
    Publisher: American Society of Civil Engineers
    Abstract: The Qi-Hay-Rood adsorption isotherm equation is shown to provide an improved description of equilibrium water vapor adsorption onto microporous activated carbon between 298 and 373 K and total pressure at 101 kPa, when compared with an existing isotherm model. The influence of temperature on the isotherm equation's parameters is also quantified. An expression for the isosteric heat of adsorption is derived from the Clausius-Clapeyron equation. It is shown that the isosteric heat of adsorption decreases with increasing temperature and increasing adsorption capacity of water vapor. This new isotherm model can be inverted to describe water vapor concentration dependence on adsorption capacity and is therefore well suited for use in dynamic models for activated-carbon adsorption systems.
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      Equilibrium and Heat of Adsorption for Water Vapor and Activated Carbon

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    http://yetl.yabesh.ir/yetl1/handle/yetl/53375
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    • Journal of Environmental Engineering

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    contributor authorShaoying Qi
    contributor authorK. James Hay
    contributor authorMark J. Rood
    contributor authorMark P. Cal
    date accessioned2017-05-08T21:29:16Z
    date available2017-05-08T21:29:16Z
    date copyrightMarch 2000
    date issued2000
    identifier other%28asce%290733-9372%282000%29126%3A3%28267%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/53375
    description abstractThe Qi-Hay-Rood adsorption isotherm equation is shown to provide an improved description of equilibrium water vapor adsorption onto microporous activated carbon between 298 and 373 K and total pressure at 101 kPa, when compared with an existing isotherm model. The influence of temperature on the isotherm equation's parameters is also quantified. An expression for the isosteric heat of adsorption is derived from the Clausius-Clapeyron equation. It is shown that the isosteric heat of adsorption decreases with increasing temperature and increasing adsorption capacity of water vapor. This new isotherm model can be inverted to describe water vapor concentration dependence on adsorption capacity and is therefore well suited for use in dynamic models for activated-carbon adsorption systems.
    publisherAmerican Society of Civil Engineers
    titleEquilibrium and Heat of Adsorption for Water Vapor and Activated Carbon
    typeJournal Paper
    journal volume126
    journal issue3
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(2000)126:3(267)
    treeJournal of Environmental Engineering:;2000:;Volume ( 126 ):;issue: 003
    contenttypeFulltext
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