Evaluation of Sonochemical Destruction of PCE in In Situ Flushing Waste Fluids

Abstract

Remediation of source zones at sites contaminated with dense non-aqueous-phase liquids using aggressive in situ flushing technologies, such as the addition of chemical additives known as cosolvents, have been implemented and successfully demonstrated in recent field tests. However, treatment of the waste fluids generated from such cleanup technologies has not received much attention. The purpose of this laboratory research was to evaluate the feasibility of using sonication as a method for treating waste fluids produced during in situ alcohol flushing at a site contaminated with a dense non-aqueous-phase liquid. Experimental results showed that sonochemical destruction of perchloroethylene (PCE) followed pseudo first-order kinetics and that increasing ethanol cosolvent percentages in the aqueous effluent resulted in decreasing degradation rates of PCE in solution. The energy efficiency (