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    Effects of Moisture on Pyrolysis of Polypropylene

    Source: Journal of Environmental Engineering:;1998:;Volume ( 124 ):;issue: 009
    Author:
    Chao-Hsiung Wu
    ,
    Ching-Yuan Chang
    ,
    Jyh-Ping Lin
    DOI: 10.1061/(ASCE)0733-9372(1998)124:9(892)
    Publisher: American Society of Civil Engineers
    Abstract: The thermal degradation kinetics of polypropylene (PP) in steam was investigated with a thermal gravimetric analysis (TGA) reaction system. The experiments were carried out in the 500–800 K temperature range at various constant heating rates of 1, 2, and 5 K/min. The partial pressure of steam in the system was adjusted to 0.24 atm, which is seen in most municipal solid waste (MSW) incinerators in Taiwan. The results indicated that the water molecule significantly enhanced the thermal degradation rate of PP. The corresponding activation energy, preexponential factor, and reaction order were determined. It was found that thermal degradation of PP in steam can be adequately described by an overall rate equation.
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      Effects of Moisture on Pyrolysis of Polypropylene

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    http://yetl.yabesh.ir/yetl1/handle/yetl/50608
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    contributor authorChao-Hsiung Wu
    contributor authorChing-Yuan Chang
    contributor authorJyh-Ping Lin
    date accessioned2017-05-08T21:25:00Z
    date available2017-05-08T21:25:00Z
    date copyrightSeptember 1998
    date issued1998
    identifier other%28asce%290733-9372%281998%29124%3A9%28892%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/50608
    description abstractThe thermal degradation kinetics of polypropylene (PP) in steam was investigated with a thermal gravimetric analysis (TGA) reaction system. The experiments were carried out in the 500–800 K temperature range at various constant heating rates of 1, 2, and 5 K/min. The partial pressure of steam in the system was adjusted to 0.24 atm, which is seen in most municipal solid waste (MSW) incinerators in Taiwan. The results indicated that the water molecule significantly enhanced the thermal degradation rate of PP. The corresponding activation energy, preexponential factor, and reaction order were determined. It was found that thermal degradation of PP in steam can be adequately described by an overall rate equation.
    publisherAmerican Society of Civil Engineers
    titleEffects of Moisture on Pyrolysis of Polypropylene
    typeJournal Paper
    journal volume124
    journal issue9
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(1998)124:9(892)
    treeJournal of Environmental Engineering:;1998:;Volume ( 124 ):;issue: 009
    contenttypeFulltext
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