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    Modeling Effects of Moisture on Adsorption Capacity of Activated Carbon for VOCs

    Source: Journal of Environmental Engineering:;1997:;Volume ( 123 ):;issue: 005
    Author:
    Ming-Shean Chou
    ,
    Jehng-Hurng Chiou
    DOI: 10.1061/(ASCE)0733-9372(1997)123:5(437)
    Publisher: American Society of Civil Engineers
    Abstract: Activated carbon has long been used for removal or recovery of volatile organic compounds (VOCs) from exhaust gas streams. Moisture content in the gas streams has been shown to be unfavorable for adsorption of VOCs; however, limited quantitative models were found in the literature. This paper reports experimental data and proposes a model concerning the effect of moisture on the adsorption capacities of a granular activated carbon (GAC) for cyclohexane and normal hexane in air streams with relative humidities (RHs), equilibrium temperatures, and VOC concentrations in the ranges of 0–0.9, 33.6–76.4°C, and 500–3,000 ppmv, respectively. Results show that within the experimental conditions the adsorption capacities of the GAC for the VOCs both in humid and dry air streams can be related to vapor pressures of the VOCs by the Langmuir model. Effect of RH on the VOC adsorption capacities are related to RHs of the air streams by the Freundlich-like model:
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      Modeling Effects of Moisture on Adsorption Capacity of Activated Carbon for VOCs

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    http://yetl.yabesh.ir/yetl1/handle/yetl/47731
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    • Journal of Environmental Engineering

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    contributor authorMing-Shean Chou
    contributor authorJehng-Hurng Chiou
    date accessioned2017-05-08T21:20:36Z
    date available2017-05-08T21:20:36Z
    date copyrightMay 1997
    date issued1997
    identifier other%28asce%290733-9372%281997%29123%3A5%28437%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/47731
    description abstractActivated carbon has long been used for removal or recovery of volatile organic compounds (VOCs) from exhaust gas streams. Moisture content in the gas streams has been shown to be unfavorable for adsorption of VOCs; however, limited quantitative models were found in the literature. This paper reports experimental data and proposes a model concerning the effect of moisture on the adsorption capacities of a granular activated carbon (GAC) for cyclohexane and normal hexane in air streams with relative humidities (RHs), equilibrium temperatures, and VOC concentrations in the ranges of 0–0.9, 33.6–76.4°C, and 500–3,000 ppmv, respectively. Results show that within the experimental conditions the adsorption capacities of the GAC for the VOCs both in humid and dry air streams can be related to vapor pressures of the VOCs by the Langmuir model. Effect of RH on the VOC adsorption capacities are related to RHs of the air streams by the Freundlich-like model:
    publisherAmerican Society of Civil Engineers
    titleModeling Effects of Moisture on Adsorption Capacity of Activated Carbon for VOCs
    typeJournal Paper
    journal volume123
    journal issue5
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(1997)123:5(437)
    treeJournal of Environmental Engineering:;1997:;Volume ( 123 ):;issue: 005
    contenttypeFulltext
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