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    Leaching Characteristics of Solidification System of C<sub>3</sub>A/CuO

    Source: Journal of Environmental Engineering:;1996:;Volume ( 122 ):;issue: 004
    Author:
    Cheng-Fang Lin
    ,
    Hwa-Wey Huang
    DOI: 10.1061/(ASCE)0733-9372(1996)122:4(323)
    Publisher: American Society of Civil Engineers
    Abstract: This study was to evaluate the leaching characteristics of a solidification/stabilization system, using a static-renewal leaching test in which the leachant was renewed periodically after intervals of static leaching. Tricalcium aluminate was selected as a solidification agent and CuO as a contaminant to simplify the solidified waste. The model solidified waste matrix was vulnerable to the renewable acetic acid (1 N) solutions. The release of Ca was rapid; in about 10 extractions, the amount of Ca released had reached the maximum. Similarly, the leaching of Al was significant; about 90% of the total Al solidified was transferred to the acetic acid solution after 10 extractions. The proton promoted surface reaction is hypothesized to be the controlling process in dissolving the calcium compounds. The dissolution reactions would enlarge the capillary pores and produce new voids in the matrix that enhance solute leaching. Since both Ca and Al hydration compounds were rapidly leached out of the solid matrix, C
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      Leaching Characteristics of Solidification System of C<sub>3</sub>A/CuO

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    http://yetl.yabesh.ir/yetl1/handle/yetl/45620
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    • Journal of Environmental Engineering

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    contributor authorCheng-Fang Lin
    contributor authorHwa-Wey Huang
    date accessioned2017-05-08T21:17:10Z
    date available2017-05-08T21:17:10Z
    date copyrightApril 1996
    date issued1996
    identifier other%28asce%290733-9372%281996%29122%3A4%28323%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/45620
    description abstractThis study was to evaluate the leaching characteristics of a solidification/stabilization system, using a static-renewal leaching test in which the leachant was renewed periodically after intervals of static leaching. Tricalcium aluminate was selected as a solidification agent and CuO as a contaminant to simplify the solidified waste. The model solidified waste matrix was vulnerable to the renewable acetic acid (1 N) solutions. The release of Ca was rapid; in about 10 extractions, the amount of Ca released had reached the maximum. Similarly, the leaching of Al was significant; about 90% of the total Al solidified was transferred to the acetic acid solution after 10 extractions. The proton promoted surface reaction is hypothesized to be the controlling process in dissolving the calcium compounds. The dissolution reactions would enlarge the capillary pores and produce new voids in the matrix that enhance solute leaching. Since both Ca and Al hydration compounds were rapidly leached out of the solid matrix, C
    publisherAmerican Society of Civil Engineers
    titleLeaching Characteristics of Solidification System of C3A/CuO
    typeJournal Paper
    journal volume122
    journal issue4
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(1996)122:4(323)
    treeJournal of Environmental Engineering:;1996:;Volume ( 122 ):;issue: 004
    contenttypeFulltext
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