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    Catalytic Ozonation of Quinoline by Prepared Fe-α-MnO2 and Ce-α-MnO2: The Role of Surface Hydroxyls and Oxygen Vacancies

    Source: Journal of Environmental Engineering:;2025:;Volume ( 151 ):;issue: 008::page 04025043-1
    Author:
    Jie Zhang
    ,
    Mengchen Zong
    ,
    Ben Dong
    ,
    Sijie Ge
    ,
    Shilong He
    DOI: 10.1061/JOEEDU.EEENG-8105
    Publisher: American Society of Civil Engineers
    Abstract: Quinoline, as one of the typical toxic and refractory organic pollutants in coal chemical industry wastewater, poses a significant threat to human health and environmental quality. In this study, MnCexOy and MnFexOy catalysts were successfully synthesized by doping Ce3+ and Fe2+ into α-MnO2 at a molar ratio of 1∶10 and were applied to the process of catalytic ozonation for the degradation of quinoline. Additionally, a variety of characterization techniques were employed to elucidate the characteristics of the catalysts, including scanning electron microscopy, X-ray diffraction, Brunauer–Emmett–Teller (BET) analysis, X-ray photoelectron spectroscopy, H2-TPR, NH3-TPD. The results show that, in the catalytic ozonation system for quinoline removal, MnCexOy demonstrates excellent quinoline removal efficiency of 87.45%, which is higher than that of MnFexOy (78.83%) and unmodified α-MnO2 (62.67%). By introducing the surface hydroxyl masking agent HPO42−, the significant role of surface hydroxyl groups and oxygen vacancies in the catalytic degradation of quinoline by MnCexOy was further demonstrated. Exploring the surface characteristics of catalysts is beneficial for continued understanding of the active centers of catalysts. Research results will be helpful to the deep treatment and reuse of tailing water of coking wastewater.
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      Catalytic Ozonation of Quinoline by Prepared Fe-α-MnO2 and Ce-α-MnO2: The Role of Surface Hydroxyls and Oxygen Vacancies

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    http://yetl.yabesh.ir/yetl1/handle/yetl/4307809
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    contributor authorJie Zhang
    contributor authorMengchen Zong
    contributor authorBen Dong
    contributor authorSijie Ge
    contributor authorShilong He
    date accessioned2025-08-17T23:02:07Z
    date available2025-08-17T23:02:07Z
    date copyright8/1/2025 12:00:00 AM
    date issued2025
    identifier otherJOEEDU.EEENG-8105.pdf
    identifier urihttp://yetl.yabesh.ir/yetl1/handle/yetl/4307809
    description abstractQuinoline, as one of the typical toxic and refractory organic pollutants in coal chemical industry wastewater, poses a significant threat to human health and environmental quality. In this study, MnCexOy and MnFexOy catalysts were successfully synthesized by doping Ce3+ and Fe2+ into α-MnO2 at a molar ratio of 1∶10 and were applied to the process of catalytic ozonation for the degradation of quinoline. Additionally, a variety of characterization techniques were employed to elucidate the characteristics of the catalysts, including scanning electron microscopy, X-ray diffraction, Brunauer–Emmett–Teller (BET) analysis, X-ray photoelectron spectroscopy, H2-TPR, NH3-TPD. The results show that, in the catalytic ozonation system for quinoline removal, MnCexOy demonstrates excellent quinoline removal efficiency of 87.45%, which is higher than that of MnFexOy (78.83%) and unmodified α-MnO2 (62.67%). By introducing the surface hydroxyl masking agent HPO42−, the significant role of surface hydroxyl groups and oxygen vacancies in the catalytic degradation of quinoline by MnCexOy was further demonstrated. Exploring the surface characteristics of catalysts is beneficial for continued understanding of the active centers of catalysts. Research results will be helpful to the deep treatment and reuse of tailing water of coking wastewater.
    publisherAmerican Society of Civil Engineers
    titleCatalytic Ozonation of Quinoline by Prepared Fe-α-MnO2 and Ce-α-MnO2: The Role of Surface Hydroxyls and Oxygen Vacancies
    typeJournal Article
    journal volume151
    journal issue8
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/JOEEDU.EEENG-8105
    journal fristpage04025043-1
    journal lastpage04025043-11
    page11
    treeJournal of Environmental Engineering:;2025:;Volume ( 151 ):;issue: 008
    contenttypeFulltext
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