Feasibility Study of Superplasticized Geopolymerization on Clayey Soil

Abstract

This study uses fly-ash-based superplasticized geopolymer by adding a naphthalene-centered superplasticizer to the geopolymerized soil. Alkali-binder ratios and alkali-activator ratios are varied simultaneously with a molarity of 10M. The optimum dosages of binder, geopolymer, and superplasticized geopolymer are found from unconfined compression tests. California Bearing Ratio (CBR), pH, consolidation, water-holding capacity, and microstructure tests were performed on optimum dosages. The clayey soil’s undrained shear strength and CBR value increased as the geopolymer was superplasticized. The 28-day undrained shear strength of geopolymerized clay was around 300 kPa, attained within three days of the curing period with superplasticized geopolymer. This is because adding a superplasticizer increases the polymerization reaction rate and improves the geopolymer’s performance. The maximum undrained shear strength was attained within seven days of the curing period for both cases. The undrained shear strength after a curing period of 7, 14, and 28 days for geopolymer and superplasticized geopolymer was found to be almost the same value, which shows that after seven days, curing has little role in strength improvement. The hydraulic conductivity and coefficient of consolidation of geopolymerized soil increased with the addition of superplasticizer due to the reduction in fine particles and plasticity of the residual soil. Microstructural studies using scanning electron microscope and x-ray diffraction techniques showed an interaction between soil, geopolymer, and superplasticizer, thus confirming the formation of geopolymer gel and increased polymerization rate with the superplasticizer.