Investigation of Chemical, Microstructural, and Rheological Perspective of Asphalt Binder Modified with Graphene Oxide

Abstract

Graphene oxide (GO) is a nanomaterial that is characterized by a two-dimensional, atomically thin, honey-combed lattice. Studies over the years have indicated potential applications of GO for improving performance characteristics of asphalt binder. This study attempts to explore the impact of GO on various chemical and rheological characteristics of unmodified asphalt binder (AC30). GO was added to AC30 over varying dosages of 1%, 2%, and 3% by weight. Carbon (C), hydrogen (H), and nitrogen (N) determinations and Fourier-transform infrared (FTIR) spectroscopy aided in understanding the chemical interaction of GO with AC30. Further, the effect of GO on dynamic viscosity was also evaluated. Rutting performance of GO-modified AC30 was studied using the multiple stress creep recovery (MSCR) test, whereas fatigue performance was evaluated based on the linear amplitude sweep (LAS) test. Additionally, yield energy GO-modified AC30 was comprehended using the binder yield energy test (BYET). CHN determination and FTIR spectroscopy indicated that modification of GO is mostly physical in nature. An improvement in aging resistivity was observed due to incorporation of GO. GO was observed to increase dynamic viscosity. Improvement in both rutting and fatigue performance of AC30 was observed but different optimum dosages of GO were obtained: 1% for maximum rutting performance and 2% for maximum fatigue performance. Enhancement in yield energy and recovery potential was also observed.