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    The Formation of Sulfate in Water Droplets

    Source: Journal of the Atmospheric Sciences:;1967:;Volume( 024 ):;issue: 001::page 54
    Author:
    Scott, W. D.
    ,
    Hobbs, P. V.
    DOI: 10.1175/1520-0469(1967)024<0054:TFOSIW>2.0.CO;2
    Publisher: American Meteorological Society
    Abstract: Previous theoretical studies of the formation of sulfate in the SO2-NH3-liquid H2O system have not considered in a rigorous manner the chemical equilibrium equations, and have failed to provide a satisfactory explanation for the catalytic action of the ammonia. In the present paper the equilibria involved are derived. By assuming that the limiting mechanism in the rate of production of sulfate is the oxidation of the sulfite ion, the observed catalysis of the oxidation by ammonia is explained. The theory also predicts a rate of production of sulfate which is in qualitative agreement with experimental results.
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      The Formation of Sulfate in Water Droplets

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    http://yetl.yabesh.ir/yetl1/handle/yetl/4150940
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    contributor authorScott, W. D.
    contributor authorHobbs, P. V.
    date accessioned2017-06-09T14:14:02Z
    date available2017-06-09T14:14:02Z
    date copyright1967/01/01
    date issued1967
    identifier issn0022-4928
    identifier otherams-15285.pdf
    identifier urihttp://onlinelibrary.yabesh.ir/handle/yetl/4150940
    description abstractPrevious theoretical studies of the formation of sulfate in the SO2-NH3-liquid H2O system have not considered in a rigorous manner the chemical equilibrium equations, and have failed to provide a satisfactory explanation for the catalytic action of the ammonia. In the present paper the equilibria involved are derived. By assuming that the limiting mechanism in the rate of production of sulfate is the oxidation of the sulfite ion, the observed catalysis of the oxidation by ammonia is explained. The theory also predicts a rate of production of sulfate which is in qualitative agreement with experimental results.
    publisherAmerican Meteorological Society
    titleThe Formation of Sulfate in Water Droplets
    typeJournal Paper
    journal volume24
    journal issue1
    journal titleJournal of the Atmospheric Sciences
    identifier doi10.1175/1520-0469(1967)024<0054:TFOSIW>2.0.CO;2
    journal fristpage54
    journal lastpage57
    treeJournal of the Atmospheric Sciences:;1967:;Volume( 024 ):;issue: 001
    contenttypeFulltext
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    DSpace software copyright © 2002-2015  DuraSpace
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