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    Prediction of Fixed‐Bed Adsorber Removal of Organics in Unknown Mixtures

    Source: Journal of Environmental Engineering:;1987:;Volume ( 113 ):;issue: 003
    Author:
    John C. Crittenden
    ,
    Paul Luft
    ,
    David W. Hand
    DOI: 10.1061/(ASCE)0733-9372(1987)113:3(486)
    Publisher: American Society of Civil Engineers
    Abstract: A method is proposed to predict fixed‐bed adsorber removal of individual organic compounds and surrogate parameters such as total organic halogen (TOX or TOC) in the presence of an unknown adsorbing mixture by representing the adsorption behavior of the unknown mixture as one or two hypothetical components (HCs). The equilibrium parameters, concentrations and mass transfer parameters of the HCs are determined by comparing the behavior of a known compound in experiments with the unknown mixture to single solute experiments. The HC properties that are determined in this manner are then used in a mathematical model of fixed‐bed adsorption to predict the breakthrough of TOX and individual compounds in the unknown mixture. This HC procedure is verified by the satisfactory agreement of fixed‐bed predictions with fixed‐bed data for six synthetic organic compounds and TOX in an unknown mixture.
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      Prediction of Fixed‐Bed Adsorber Removal of Organics in Unknown Mixtures

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    http://yetl.yabesh.ir/yetl1/handle/yetl/34497
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    • Journal of Environmental Engineering

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    contributor authorJohn C. Crittenden
    contributor authorPaul Luft
    contributor authorDavid W. Hand
    date accessioned2017-05-08T20:59:19Z
    date available2017-05-08T20:59:19Z
    date copyrightJune 1987
    date issued1987
    identifier other%28asce%290733-9372%281987%29113%3A3%28486%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/34497
    description abstractA method is proposed to predict fixed‐bed adsorber removal of individual organic compounds and surrogate parameters such as total organic halogen (TOX or TOC) in the presence of an unknown adsorbing mixture by representing the adsorption behavior of the unknown mixture as one or two hypothetical components (HCs). The equilibrium parameters, concentrations and mass transfer parameters of the HCs are determined by comparing the behavior of a known compound in experiments with the unknown mixture to single solute experiments. The HC properties that are determined in this manner are then used in a mathematical model of fixed‐bed adsorption to predict the breakthrough of TOX and individual compounds in the unknown mixture. This HC procedure is verified by the satisfactory agreement of fixed‐bed predictions with fixed‐bed data for six synthetic organic compounds and TOX in an unknown mixture.
    publisherAmerican Society of Civil Engineers
    titlePrediction of Fixed‐Bed Adsorber Removal of Organics in Unknown Mixtures
    typeJournal Paper
    journal volume113
    journal issue3
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(1987)113:3(486)
    treeJournal of Environmental Engineering:;1987:;Volume ( 113 ):;issue: 003
    contenttypeFulltext
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