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    The Solubility of Copper and Its Oxides in Supercritical Steam

    Source: Journal of Engineering for Gas Turbines and Power:;1963:;volume( 085 ):;issue: 001::page 33
    Author:
    F. J. Pocock
    ,
    J. F. Stewart
    DOI: 10.1115/1.3675213
    Publisher: The American Society of Mechanical Engineers (ASME)
    Abstract: This paper contains a study of the solubility of copper and its oxides in supercritical steam which was undertaken because of difficulties experienced with copper deposition in the high-pressure turbine of the Ohio Power Company’s Philo 6 supercritical steam-generating cycle. This study shows that copper has appreciable solubility in superheated supercritical steam. The extent of solubility is apparently a function of the oxidation state of the metal, with the highest state of oxidation (CuO) showing the greatest solubility. A slightly increased solubility was effected by increasing pH values from ∼7.5 to ∼9.5 with ammonia. It is also shown that copper solubility is principally a function of pressure over the narrow temperature range tested (900–1150 F) probably because this parameter has the greatest effect on specific volume.
    keyword(s): Copper , Steam , oxidation , Superheating , Pressure , Temperature , Metals , High pressure (Physics) , Turbines AND Cycles ,
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      The Solubility of Copper and Its Oxides in Supercritical Steam

    URI
    https://yetl.yabesh.ir/yetl1/handle/yetl/94589
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    • Journal of Engineering for Gas Turbines and Power

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    contributor authorF. J. Pocock
    contributor authorJ. F. Stewart
    date accessioned2017-05-08T23:11:12Z
    date available2017-05-08T23:11:12Z
    date copyrightJanuary, 1963
    date issued1963
    identifier issn1528-8919
    identifier otherJETPEZ-26627#33_1.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/94589
    description abstractThis paper contains a study of the solubility of copper and its oxides in supercritical steam which was undertaken because of difficulties experienced with copper deposition in the high-pressure turbine of the Ohio Power Company’s Philo 6 supercritical steam-generating cycle. This study shows that copper has appreciable solubility in superheated supercritical steam. The extent of solubility is apparently a function of the oxidation state of the metal, with the highest state of oxidation (CuO) showing the greatest solubility. A slightly increased solubility was effected by increasing pH values from ∼7.5 to ∼9.5 with ammonia. It is also shown that copper solubility is principally a function of pressure over the narrow temperature range tested (900–1150 F) probably because this parameter has the greatest effect on specific volume.
    publisherThe American Society of Mechanical Engineers (ASME)
    titleThe Solubility of Copper and Its Oxides in Supercritical Steam
    typeJournal Paper
    journal volume85
    journal issue1
    journal titleJournal of Engineering for Gas Turbines and Power
    identifier doi10.1115/1.3675213
    journal fristpage33
    journal lastpage44
    identifier eissn0742-4795
    keywordsCopper
    keywordsSteam
    keywordsoxidation
    keywordsSuperheating
    keywordsPressure
    keywordsTemperature
    keywordsMetals
    keywordsHigh pressure (Physics)
    keywordsTurbines AND Cycles
    treeJournal of Engineering for Gas Turbines and Power:;1963:;volume( 085 ):;issue: 001
    contenttypeFulltext
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    DSpace software copyright © 2002-2015  DuraSpace
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