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    Effect of Redox Potential and pH on TNT Transformation in Soil-Water Slurries

    Source: Journal of Environmental Engineering:;1997:;Volume ( 123 ):;issue: 010
    Author:
    Cynthia B. Price
    ,
    James M. Brannon
    ,
    Charolett A. Hayes
    DOI: 10.1061/(ASCE)0733-9372(1997)123:10(988)
    Publisher: American Society of Civil Engineers
    Abstract: The presence of 2,4,6-trinitrotoluene (TNT) and its transformation products in surface soil, the vadose zone, and ground water can present serious environmental problems. This situation is exacerbated because the processes that control the mobility and transformation of TNT are not well understood. The objective of this study was to determine the effects of redox potential (Eh) and pH on the fate and transformation of TNT in soil. An initial investigation of soil components responsible for the observed TNT transformation was also conducted. Laboratory investigations consisted of testing at four separate redox potentials and four pH levels. An 18:1 (water:soil) suspension spiked with 100 μg/g TNT was used. Results indicated that TNT was unstable under all redox and pH conditions, and was least stable under highly reducing conditions at all four pH values. Greater amounts of TNT were incorporated into soil organic matter under anaerobic than under aerobic conditions. Results of the soil component study indicated that the presence of Fe
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      Effect of Redox Potential and pH on TNT Transformation in Soil-Water Slurries

    URI
    https://yetl.yabesh.ir/yetl1/handle/yetl/46931
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    • Journal of Environmental Engineering

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    contributor authorCynthia B. Price
    contributor authorJames M. Brannon
    contributor authorCharolett A. Hayes
    date accessioned2017-05-08T21:19:16Z
    date available2017-05-08T21:19:16Z
    date copyrightOctober 1997
    date issued1997
    identifier other%28asce%290733-9372%281997%29123%3A10%28988%29.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/46931
    description abstractThe presence of 2,4,6-trinitrotoluene (TNT) and its transformation products in surface soil, the vadose zone, and ground water can present serious environmental problems. This situation is exacerbated because the processes that control the mobility and transformation of TNT are not well understood. The objective of this study was to determine the effects of redox potential (Eh) and pH on the fate and transformation of TNT in soil. An initial investigation of soil components responsible for the observed TNT transformation was also conducted. Laboratory investigations consisted of testing at four separate redox potentials and four pH levels. An 18:1 (water:soil) suspension spiked with 100 μg/g TNT was used. Results indicated that TNT was unstable under all redox and pH conditions, and was least stable under highly reducing conditions at all four pH values. Greater amounts of TNT were incorporated into soil organic matter under anaerobic than under aerobic conditions. Results of the soil component study indicated that the presence of Fe
    publisherAmerican Society of Civil Engineers
    titleEffect of Redox Potential and pH on TNT Transformation in Soil-Water Slurries
    typeJournal Paper
    journal volume123
    journal issue10
    journal titleJournal of Environmental Engineering
    identifier doi10.1061/(ASCE)0733-9372(1997)123:10(988)
    treeJournal of Environmental Engineering:;1997:;Volume ( 123 ):;issue: 010
    contenttypeFulltext
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