Mechanism of Chemical Environment on Compression and Shear Strength of Compacted Loess: A Case Study from Chinese Loess Plateau

Abstract

The mechanical properties of loess are strongly dependent on the environment where it is deposited. To investigate the effects of acidic, alkaline, and saline environments on the strength and deformation properties of compacted loess, the consolidation test and direct shear test were carried out on loess samples contaminated with different concentrations of acetic acid, sodium hydroxide, and sodium sulfate. In addition, changes in zeta potential, mineralogy, chemical composition, and microstructure of the loess samples at different chemical environments were also measured. The results show that the reduction in the thickness of the diffuse double layer for the loess contaminated with acetic acid leads to the aggregation of clay particles, laying the foundation for the expansion of loess pores, while the dissolution of carbonate cement and chemical cement makes the soil structure looser. Hence, the compacted loess has significantly lower shear strength and higher compressibility in an acidic environment. The mechanical properties in the saline environment show similar variation characteristics to the acidic environment, but this is mainly due to carbonate solubilization. In the alkaline environment, the degree of interparticle cementation of the loess is enhanced by the generation of calcite due to dedolomitization and the generation of colloidal flocs of Al(OH)3, Fe(OH)3, and H2SiO3. In addition, the pore connectivity is greatly reduced by the extensive distribution of clay particles caused by the development of a diffuse double layer. As a result, its compressibility and shear strength are improved compared to uncontaminated loess. These findings can be used as a reference for geoengineering practice in loess areas.