Estimation of Ultraviolet-A Irradiance from Measurements of 368-nm Spectral Irradiance

Abstract

The estimation of ultraviolet-A (UV-A) radiation across the earth?s surface is needed to model plant productivity and future impacts of ultraviolet-B radiation on plant productivity. We have developed two models to estimate the UV-A irradiance from measurements of the diffuse and global spectral irradiance at 368 nm. The models were developed from 30-min-interval measurements made throughout 2000 at three locations across the United States and evaluated from 30-min measurements made throughout 2000 at three additional locations and throughout 2001 and 2002 at seven locations. UV-A irradiance was best estimated from measured global 368-nm irradiance and empirical functions defining the UV-A and 368-nm irradiance values estimated from a theoretical pseudospherical two-stream discrete-ordinates radiative transfer model. The radiative transfer model provided baseline irradiance relationships between UV-A irradiance and 368-nm spectral irradiance. The semiempirical model estimated the UV-A irradiance at seven locations across the United States with a mean bias error of 0.5 W m?2 and a root-mean-square error of 2 W m?2, corresponding to approximately ±4% of a clear-sky irradiance of 50 W m?2 for a solar zenith angle of 30°. This model error was comparable to the combined effect of previously estimated UV-A and 368-nm irradiance measurement errors.