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    Influence of Crosslinking on the Plastic Behavior of Amorphous Polymers at Large Strains

    Source: Journal of Engineering Materials and Technology:;1997:;volume( 119 ):;issue: 003::page 223
    Author:
    Christian G’Sell
    ,
    Abdelhamid Souahi
    DOI: 10.1115/1.2812248
    Publisher: The American Society of Mechanical Engineers (ASME)
    Abstract: The mechanical properties of three grades of PMMA, one linear and two crosslinked, are investigated in tension below and above the glass transition temperature. It is found that strain-hardening decreases gradually with temperature in the glassy state, but keeps a significant value in the rubbery state. The results are analyzed in terms of an entropy-based statistical model (van der Giessen and Wu, 1992) which describes the stress-strain response of a chain network. The junctions of the network are not only associated with the chemical crosslinks, but additionally with physical entanglements, which are more numerous in the glassy state.
    keyword(s): Temperature , Stress , Entropy , Mechanical properties , Chain , Polymers , Glass transition , Junctions , Networks , Tension AND Work hardening ,
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      Influence of Crosslinking on the Plastic Behavior of Amorphous Polymers at Large Strains

    URI
    https://yetl.yabesh.ir/yetl1/handle/yetl/118773
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    contributor authorChristian G’Sell
    contributor authorAbdelhamid Souahi
    date accessioned2017-05-08T23:53:37Z
    date available2017-05-08T23:53:37Z
    date copyrightJuly, 1997
    date issued1997
    identifier issn0094-4289
    identifier otherJEMTA8-26986#223_1.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/118773
    description abstractThe mechanical properties of three grades of PMMA, one linear and two crosslinked, are investigated in tension below and above the glass transition temperature. It is found that strain-hardening decreases gradually with temperature in the glassy state, but keeps a significant value in the rubbery state. The results are analyzed in terms of an entropy-based statistical model (van der Giessen and Wu, 1992) which describes the stress-strain response of a chain network. The junctions of the network are not only associated with the chemical crosslinks, but additionally with physical entanglements, which are more numerous in the glassy state.
    publisherThe American Society of Mechanical Engineers (ASME)
    titleInfluence of Crosslinking on the Plastic Behavior of Amorphous Polymers at Large Strains
    typeJournal Paper
    journal volume119
    journal issue3
    journal titleJournal of Engineering Materials and Technology
    identifier doi10.1115/1.2812248
    journal fristpage223
    journal lastpage227
    identifier eissn1528-8889
    keywordsTemperature
    keywordsStress
    keywordsEntropy
    keywordsMechanical properties
    keywordsChain
    keywordsPolymers
    keywordsGlass transition
    keywordsJunctions
    keywordsNetworks
    keywordsTension AND Work hardening
    treeJournal of Engineering Materials and Technology:;1997:;volume( 119 ):;issue: 003
    contenttypeFulltext
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