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    The Action of Neutral Organic Phosphates as EP Additives

    Source: Journal of Fluids Engineering:;1965:;volume( 087 ):;issue: 003::page 761
    Author:
    F. T. Barcroft
    ,
    S. G. Daniel
    DOI: 10.1115/1.3650676
    Publisher: The American Society of Mechanical Engineers (ASME)
    Abstract: A radiochemical analysis has been made of the EP film formed on the surfaces of the tappets of an engine lubricated with an oil containing triphenyl phosphate, labeled with phosphorus –32, as the EP additive. The results do not support the widely held view that phosphate esters owe their effectiveness as EP additives to the formation of phosphide eutectics of low melting point on metal surfaces. The results indicate the presence of metal phosphates and metal organophosphates formed from acid-phosphate intermediates derived from the ester. These findings, together with the results of subsequent rig tests, suggest that the effectiveness of neutral organic phosphates as EP additives depends on the ease with which they hydrolyze on the metal surface to form acid phosphates; the more readily the ester hydrolyzes the better its performance.
    keyword(s): Metals , Engines , Metal surfaces , Ester AND Melting point ,
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      The Action of Neutral Organic Phosphates as EP Additives

    URI
    https://yetl.yabesh.ir/yetl1/handle/yetl/107367
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    contributor authorF. T. Barcroft
    contributor authorS. G. Daniel
    date accessioned2017-05-08T23:33:25Z
    date available2017-05-08T23:33:25Z
    date copyrightSeptember, 1965
    date issued1965
    identifier issn0098-2202
    identifier otherJFEGA4-27261#761_1.pdf
    identifier urihttp://yetl.yabesh.ir/yetl/handle/yetl/107367
    description abstractA radiochemical analysis has been made of the EP film formed on the surfaces of the tappets of an engine lubricated with an oil containing triphenyl phosphate, labeled with phosphorus –32, as the EP additive. The results do not support the widely held view that phosphate esters owe their effectiveness as EP additives to the formation of phosphide eutectics of low melting point on metal surfaces. The results indicate the presence of metal phosphates and metal organophosphates formed from acid-phosphate intermediates derived from the ester. These findings, together with the results of subsequent rig tests, suggest that the effectiveness of neutral organic phosphates as EP additives depends on the ease with which they hydrolyze on the metal surface to form acid phosphates; the more readily the ester hydrolyzes the better its performance.
    publisherThe American Society of Mechanical Engineers (ASME)
    titleThe Action of Neutral Organic Phosphates as EP Additives
    typeJournal Paper
    journal volume87
    journal issue3
    journal titleJournal of Fluids Engineering
    identifier doi10.1115/1.3650676
    journal fristpage761
    journal lastpage767
    identifier eissn1528-901X
    keywordsMetals
    keywordsEngines
    keywordsMetal surfaces
    keywordsEster AND Melting point
    treeJournal of Fluids Engineering:;1965:;volume( 087 ):;issue: 003
    contenttypeFulltext
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