Ni–Fe Alloy-Supported Intermediate Temperature SOFCs Using LaGaO3 Electrolyte Film for Quick Startup

Abstract

Intermediate temperature solid oxide fuel cells (SOFCs), which are highly tolerant against a thermal cycle, are studied by using the Ni–Fe porous alloy substrate prepared by an in situ reduction. It was found that Ni–Fe alloy exhibits high activity against anodic reaction and suitable compatibility with LaGaO3 electrolyte. The electrolyte film of La0.9Sr0.1Ga0.8Mg0.2O3 (LSGM) and Sm0.2Ce0.8O2 (SDC) bilayer with 5μm thickness was successfully prepared on the dense NiO–Fe2O3 composite anode. After a in situ reduction, the dense plate of NiO–Fe2O3 was changed to the porous Ni–Fe alloy substrate; however, the LSGM film can keep the dense state. The prepared Ni–Fe alloy that supported LSGM cell demonstrated the maximum power densities of 0.9W∕cm2 and 0.4W∕cm2 at 873K and 573K. After heating up to 873K within 540s, there is no crack formed on the film and almost the theoretical open circuit voltage was exhibited. In addition, the maximum power density of 400mW∕cm2 was achieved at 773K. After the thermal cycling, the decrease in the maximum power density was not large, and this suggests that the film is still gas tight and highly tolerant against the thermal cycle. Quick start characteristics of the metal support SOFC could expand the SOFC application to the electric source of a mobile-field-like automobile.