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contributor authorFinnegan, William G.
contributor authorChai, Steven K.
date accessioned2017-06-09T14:38:13Z
date available2017-06-09T14:38:13Z
date copyright2003/07/01
date issued2003
identifier issn0022-4928
identifier otherams-23292.pdf
identifier urihttp://onlinelibrary.yabesh.ir/handle/yetl/4159837
description abstractA potential molecular mechanism of ice nucleation on AgI and AgI?·?AgCl particulates involves rearrangement of ordered water molecule clusters associated with hydrated Ag+ ion patches. This nucleation mechanism is thought to occur rapidly at ?5° to ?20°C on substrate particles wetted by water. This hypothesis is based on analysis of the rates of ice crystal formation and ice nucleus activities observed in experiments previously conducted in a 1-m3 isothermal cloud chamber using chemical kinetics. These experiments examined the chemistry of wetted AgI colloid particles involving electric charge separations between the particles and adjacent solution. The rate of nucleation is slowed by the presence of alkali and alkaline earth halides in concentrations greater than approximately 10?3 M in the water wetting the particles. Match of the crystal structure of the substrate with that of the ice may have no effect on this mechanism.
publisherAmerican Meteorological Society
titleA New Hypothesis for the Mechanism of Ice Nucleation on Wetted AgI and AgI·AgCl Particulate Aerosols
typeJournal Paper
journal volume60
journal issue14
journal titleJournal of the Atmospheric Sciences
identifier doi10.1175/1520-0469(2003)060<1723:ANHFTM>2.0.CO;2
journal fristpage1723
journal lastpage1731
treeJournal of the Atmospheric Sciences:;2003:;Volume( 060 ):;issue: 014
contenttypeFulltext


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