Experimental Determination of Spectral Transmittance of Porous Cerium Dioxide in the Range 900–1700 nm

Abstract

Overall transmittance of porous cerium dioxide is measured in the spectral range of 900–1700 nm using dispersive spectroscopy. Dense and porous samples of cerium dioxide with average porosities of 0.08 and 0.72, respectively, are investigated. The transmittance of both sample types increases with decreasing thickness, and this trend is more pronounced for the dense samples. The on-average spectrally increasing transmittance of the dense samples is attributed to the decreasing absorption by bulk cerium dioxide with radiation wavelength. The transmittance of the porous samples, on the other hand, remains approximately constant over the spectrum. Porous samples attenuate radiation stronger than the dense samples at any wavelength in the considered range, and it is hypothesized that this effect is due to more intense scattering. Sharp local variations of the transmittance are observed for both sample types.